I used 'id' command to check current user info and compare that with the ownership of the directories in old /home. I may be able to write a simple shell script to do this.
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This is not Windows which generates unique hashes for its user-based security.
If you simply point to your /home during your installation, your new User created during the new installation will use the old /home just fine without any special configuration.
I don't know your purposes for migrating your old Users to your new install, any local Users can be set up the same way, or simply create a new User and copy the old /home content to the new location. If you're talking about remote access to network shares, then it will depend on how security is set up for that network share.
Keep in mind that a commonly used rule of thumb is that if you're dealing with 3 Users or less, doing extra work to migrate and automate is generally not worthwhile compared to simply creating new Users and manually migrating data, configuration and apps. If you're dealing with 3 or more Users, then it might be worth spending the extra time to prep your migration and do it as efficiently as possible. So, 3 Users is the threshold when you could choose either option, it's a break even proposition.
My personal experience upgrading so many versions at once and especially for anything earlier than and including 13.1 has a fairly poor record... Even when I thought it worked, within a couple weeks problems would show up. If you want to try to upgrade from 13.1 again (Do you have a full backup?), I or someone else can outline a step by step way to upgrade which should be more successful. Before doing any upgrade though, you need to identify apps which will need to be upgraded separately... Are these simple workstations or are any Server apps running on them like webservers, database apps?
TSU